Environmental geological assessment of naturally occurring asbestos based on mineralogical and spatial analysis: The Bajgora-Mitrovicë Area, Kosovo
Bahri Sinani1, Blazo Boev2, Arianit Reka3,4, Berat Sinani2, Ivan Boev2
1Department of Environmental Engineering, Faculty of Natural and Technical Science, University “Goce Delchev”, Shtip, North Macedonia
2Department of Petrology, Mineralogy and Geochemistry, Faculty of Natural and Technical Science, University “Goce Delchev”, Shtip, North Macedonia
3Department of Chemistry, Faculty of Natural Sciences and Mathematics, University of Tetova, Tetovo, North Macedonia
4Albanian Unit of Nanoscience and Nanotechnology, NanoAlb, Academy of Sciences of Albania, Tirana, Albania
Min. miner. depos. 2026, 20(1):28-40
https://doi.org/10.33271/mining20.01.028
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      ABSTRACT
      Purpose. To evaluate the spatial distribution and mineralogical variability of naturally occurring asbestos (NOA) in the Bajgora region and assess its environmental significance in relation to geological conditions and current land-use patterns, to identify asbestos-bearing zones and provide a spatial basis for environmental hazard assessment.
      Methods. A combined mineralogical, statistical, and geospatial approach was applied. Twenty representative rock samples were collected across the study area and analyzed using X-ray powder diffraction (XRD) and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDX) to identify and quantify asbestos-related mineral phases. Descriptive statistics, correlation analysis, and principal component analysis (PCA) were used to evaluate mineralogical variability and phase associations. Spatial interpolation using Kriging was performed in GIS software to visualize the distribution of serpentine-group minerals and chrysotile and to support environmental hazard zoning.
      Findings. The results indicate pronounced mineralogical heterogeneity within the Bajgora region, dominated by serpentine-group minerals, including lizardite (with multiple polytypes), antigorite, and subordinate chrysotile. Lizardite is the most widespread phase, reflecting low-temperature serpentinization, whereas antigorite locally dominates under higher-temperature, higher-pressure conditions. Chrysotile occurs discontinuously and is spatially restricted to specific structural zones, such as fracture systems and lithological contacts. Statistical and multivariate analyses confirm non-random spatial patterns and strong geological control on mineral distribution.
      Originality. This study provides one of the first integrated mineralogical-statistical-spatial assessments of NOA in the Bajgora region, linking detailed phase characterization with spatial modeling to support site-specific environmental risk evaluation in ophiolitic terrains of the Western Balkans.
      Practical implications. The generated spatial distribution maps provide a practical tool for environmental risk zoning, land-use planning, and prioritizing monitoring and mitigation measures in areas affected by naturally occurring asbestos.
      Keywords: naturally occurring asbestos; chrysotile; serpentine minerals; spatial analysis; environmental hazard zoning
      REFERENCES
- Sinani, B., Boev, B., Reka, A.A., Sinani, B., & Boev, I. (2025). Distribution of naturally occurring asbestos in the Mitrovica region: Geochemical and mineralogical characterization. Geosciences, 15(9), 335. https://doi.org/10.3390/geosciences15090335
- Evans, B.W. (2004). The serpentinite multisystem revisited: Chrysotile is metastable. International Geology Review, 46(6), 479-506. https://doi.org/10.2747/0020-6814.46.6.479
- Raimbekova, A., Kapralova, V., Popova, A., Kubekova, S., Dalbanbay, A., Kalenova, A., Mustahimov, B., Yermekbayeva, S., & Myrzabekova, S. (2024). Corrosion behavior of mild steel in sodium sulfate solution in presence of phosphates of different composition. Journal of Chemical Technology and Metallurgy, 59(2), 367-377. https://doi.org/10.59957/jctm.v59.i2.2024.16
- Viirta, R.L. (2006). Worldwide asbestos supply and consumption trends from 1900 through 2003. Circular, 1298, 80. https://doi.org/10.3133/cir1298
- Wilk, E., Krówczyńska, M., & Zagajewski, B. (2019). Modelling the spatial distribution of asbestos-cement products in Poland with the use of the random forest algorithm. Sustainability, 11(16), 4355. https://doi.org/10.3390/su11164355
- Kezembayeva, G., Rysbekov, K., Dyussenova, Z., Zhumagulov, A., Umbetaly, S., Barmenshinova, M., Yerkezhan, B., & Zhakypbek, Y. (2025). Public health risk assessment of quantitative emission from a molybdenum production plant: Case study of Kazakhstan. Engineered Science, 34, 1454. https://doi.org/10.30919/es1454
- Bekbassarov, S., Soltabaeva, S., Daurenbekova, A., & Ormanbekova, A. (2015). “Green” economy in mining. New Developments in Mining Engineering, 431-434. https://doi.org/10.1201/b19901-75
- Shults, R., Seitkazina, G., Annenkov, A., Demianenko, R., Soltabayeva, S., Kozhayev, Z., & Orazbekova, G. (2025). Complex geodetic monitoring of the massive sports structures by terrestrial laser scanning. Civil Engineering Journal, 11(3), 884-909. https://doi.org/10.28991/CEJ-2025-011-03-05
- Baimukhanbetova, E., Onaltayev, D., Daumova, G., Amralinova, B., & Amangeldiyev, A. (2020). Improvement of informational technologies in ecology. E3S Web of Conferences, 159, 01008. https://doi.org/10.1051/e3sconf/202015901008
- Meholli, B. (2014). Ophiolitic magmatism and new magmatism in the Bajgora region, mineral resources associated with them. PhD Dissertation. Tiranë, Albania: Polytechnic University of Tirana.
- Nazirova, A., Kalimoldayev, M., Abdoldina, F., & Dubovenko, Y. (2022). Optimization of an information system module for solving a direct gravimetry problem using a genetic algorithm. Eastern-European Journal of Enterprise Technologies, 2(9(116)), 21-34. https://doi.org/10.15587/1729-4061.2022.253976
- Abdoldina, F.N., Nazirova, A.N., Dubovenko, Y.I., & Umirova, G.K. (2020). On the solution of the gravity direct problem for a prism with a simulated annealing approach. Geomodel 2020, 1, 1-5. https://doi.org/10.3997/2214-4609.202050014
- Dubovenko, Y.I., Nazirova, A.B., & Abdoldina, F.N. (2022). Data-driven preprocessing of gravity data in oilfield GIS monitoring system in Kazakhstan. International Conference Monitoring of Geological Processes and Ecological Condition of the Environment, 1, 1-4. https://doi.org/10.3997/2214-4609.2022580267
- Abdoldina, F., Nazirova, A., Dubovenko, Y., & Umirova, G. (2020). On the solution of the gravity direct problem for a sphere with a simulated annealing approach. International Multidisciplinary Scientific GeoConference, 20(2.1), 239-245. https://doi.org/10.5593/sgem2020/2.1/s07.031
- Adu, S.A., Gyang, P.A., & Yakin, Z. (2025). The role of GIS and spatial analysis in enhancing urban resilience and disaster response for vulnerable US communities. World Journal of Advanced Research and Reviews, 27(1), 746-754. https://doi.org/10.30574/wjarr.2025.27.1.2567
- Toljić, M., Stojadinović, U., & Krstekanic, N. (2019). Vardar zone: New insights into the tectono-depositional subdivision. II Geological Congress of Bosnia and Herzegovina, 60-73.
- Bilalli, B., Gawlick, H.J., Prela, M., & Uta, A. (2025). Ophiolitic mélanges in southeastern Kosovo. Tiranë, Albania: Polytechnic University of Tirana.
- Hengl, T. (2007). A practical guide to geostatistical mapping of environmental variables (EUR 22904 EN). Office for Official Publications of the European Communities. Retrived from: https://publications.jrc.ec.europa.eu/repository/handle/JRC38153
- Zelic, M., Marroni, M., Pandolfi, L., & Trivić, B. (2010). Tectonic setting of the Vardar suture zone (Dinaric-Hellenic belt): The example of the Kopaonik area (Southern Serbia). Ofioliti, 35(1), 49-69.
- Robertson, A.H.F., & Karamata, S. (1994). The role of subduction-accretion processes in the tectonic evolution of the Mesozoic Tethys in Serbia. Tectonophysics, 234(1-2), 73-94. https://doi.org/10.1016/0040-1951(94)90205-4
- Ahmadi, H., Hussaini, M.R., Yousufi, A., Bekbotayeva, A., Baisalova, A., Amralinova, B., Mataibayeva, I., Rahmani, A.B., Pekkan, E., & Sahak, N. (2023). Geospatial insights into ophiolitic complexes in the Cimmerian realm of the Afghan Central Block (Middle Afghanistan). Minerals, 13(11), 1453. https://doi.org/10.3390/min13111453
- Robertson, A.H., Trivić, B., Đerić, N., & Bucur, I.I. (2013). Tectonic development of the Vardar ocean and its margins: Evidence from the Republic of Macedonia and Greek Macedonia. Tectonophysics, 595, 25-54. https://doi.org/10.1016/j.tecto.2012.07.022
- Schmid, S.M., Fügenschuh, B., Kounov, A., Maţenco, L., Nievergelt, P., Oberhänsli, R., & Van Hinsbergen, D.J. (2020). Tectonic units of the Alpine collision zone between Eastern Alps and western Turkey. Gondwana Research, 78, 308-374. https://doi.org/10.1016/j.gr.2019.07.005
- Schmid, S.M., Bernoulli, D., Fügenschuh, B., Matenco, L., Schefer, S., Schuster, R., & Ustaszewski, K. (2008). The Alpine-Carpathian-Dinaridic orogenic system: Correlation and evolution of tectonic units. Swiss Journal of Geosciences, 101(1), 139-183. https://doi.org/10.1007/s00015-008-1247-3
- Sinani, B., Boev, B., Reka, A.A., Sinani, B., & Boev, I. (2025). GTMod 1.0: A geological and geotectonic tool for ore body modeling-case study of the Trepça mine. Earth Science Informatics, 18(4), 1-13. https://doi.org/10.1007/s12145-025-02038-x
- Karamata, S. (2006). The geological development of the Balkan Peninsula related to the approach, collision and compression of Gondwanan and Eurasian units. Geological Society, London, Special Publications, 260(1), 155-178. https://doi.org/10.1144/GSL.SP.2006.260.01.07
- Mehana, Y. (2024). Research of the presence of heavy metals in drinking water in the villages of Kelmend, Zhazhë, Boletin, Melenicë, Vllahi, Maxherë, Zjaqë. MSc Thesis. Mitrovicë, Kosovo: University “Isa Boletini”.
- Elezaj, Z., & Kodra, A. (2008). Geology of Kosovo. Pristina, Kosovo: University of Pristina.
- State Archives of Kosovo. (2025). Geological research in Kosovo: Research program for 1980-1981, Geological survey of Yugoslavia. State Archives of Kosovo. Retrived from: https://katalogu-ashak.net/user-view-search
- Study of Asbestos in Kosovo. (1973). Pristina, Kosovo: Institute for Geological and Geophysical Research.
- Manyama, M.T., Hepelwa, A.S., & Nahonyo, C.L. (2019). Analysis of socio-ecological impacts of built environment at Dar es Salaam Metropolitan Coastline, Tanzania. Open Journal of Social Sciences, 7(10), 161-182. https://doi.org/10.4236/jss.2019.710014
- Kruasom, T., Ngeoywijit, S., Sopapol, S., Kosanlawit, T., Sangwarn, S., & Adthajak, P. (2025). From foundations to frontiers: The development and future of structural equation modeling (SEM). UMT-Poly Journal, 22(2), 129-149.
- Plichko, L.V., Zatserkovnyi, V.I., Khilchevskyi, V.K., Mizernaya, M., & Bakytzhan, A. (2020). Assessment of changes a number of surface water bodies within the sub-basin of the Desna River using remote sensing materials. Geoinformatics: Theoretical and Applied Aspects, 1, 1-5. https://doi.org/10.3997/2214-4609.2020geo101
- Shults, R., Soltabayeva, S., Seitkazina, G., Nukarbekova, Z., & Kucherenko, O. (2020). Geospatial monitoring and structural mechanics models: A case study of sports structures. Environmental Engineering, 11, 1-9. https://doi.org/10.3846/enviro.2020.685
- Akinboyewa, T., Li, Z., Ning, H., & Lessani, M.N. (2025). GIS copilot: Towards an autonomous GIS agent for spatial analysis. International Journal of Digital Earth, 18(1), 2497489. https://doi.org/10.1080/17538947.2025.2497489
- Sadykov, B.B., Baygurin, Zh.D., Altayeva, A.A., Kozhaev, Zh.Т., & Stelling, W. (2019). New approach to zone division of surface of the deposit by the degree of sinkhole risk. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, 6, 31-35. https://doi.org/10.29202/nvngu/2019-6/5
- Nizamova, A.T., Rasulov, A.K., & Maxmadiyev, D.R. (2025). Assessment of industrial waste disposal practices in the mining sector of Uzbekistan. Engineering Journal of Satbayev University, 147(4), 23-29. https://doi.org/10.51301/ejsu.2025.i4.04
- Liu, Q., Liu, G., Chen, W., & Chen, G. (2021). HMCA-сontour: A visual basic program based on surfer automation for soil heavy metal spatial distribution and contamination assessment mapping. Sustainability, 13(4), 2282. https://doi.org/10.3390/su13042282
- Pour, A.B., Parsa, M., & Eldosouky, A.M. (2023). Introduction to mineral exploration. Geospatial Analysis Applied to Mineral Exploration, 1-16. https://doi.org/10.1016/B978-0-323-95608-6.00001-9
- Balaram, V., & Subramanyam, K.S.V. (2022). Sample preparation for geochemical analysis: Strategies and significance. Advances in Sample Preparation, 1, 100010. https://doi.org/10.1016/j.sampre.2022.100010
- Balaram, V. (2021). Current and emerging analytical techniques for geochemical and geochronological studies. Geological Journal, 56(5), 2300-2359. https://doi.org/10.1002/gj.4005
- Park, C.S., Shin, H.S., Oh, H., Cho, H., & Cheong, A.C.S. (2016). Trace element analysis of whole-rock glass beads of geological reference materials by Nd: YAG UV 213 nm LA-ICP-MS. Journal of Analytical Science and Technology, 7(1), 15. https://doi.org/10.1186/s40543-016-0094-5
- Ceci, A., Costanza, G., & Tata, M.E. (2025). Microstructural and XRD investigations on Zn after plastic deformation. Crystals, 15(10), 908. https://doi.org/10.3390/cryst15100908
- Wicks, F.J., & Whittaker, E.J.W. (1977). Serpentine textures and serpentinization. The Canadian Mineralogist, 15(4), 459-488.
- Evans, B.W. (2004). The serpentinite multisystem revisited: Chrysotile is metastable. International Geology Review, 46(6), 479-506. https://doi.org/10.2747/0020-6814.46.6.479
- Mellini, M. (2013). Structure and microstructure of serpentine minerals. EMU Notes in Mineralogy, 14, 1-27. https://doi.org/10.1180/EMU-notes.14.5
- Mellini, M., & Zanazzi, P.F. (1987). Crystal structures of lizardite-1T and lizardite-2H1 from Coli, Italy. American Mineralogist, 72(9-10), 943-948.
- Mambetaliyeva, A.R., Mamyrbayeva, K.K., Turysbekov, D.K., Dauletbakov, T.S., & Barmenshinova, M.B. (2022). Investigation of the process of sulfiding of gold-arsenic containing ores and concentrates. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, 3, 51-56. https://doi.org/10.33271/nvngu/2022-3/051
- Rinaudo, C., Gastaldi, D., & Belluso, E. (2003). Characterization of chrysotile, antigorite and lizardite by FT-Raman spectroscopy. The Canadian Mineralogist, 41(4), 883-890. https://doi.org/10.2113/gscanmin.41.4.883
- Shirokiy, P.G., Zavaley, V.A., Auelkhan, Y.S., & Alzhigitova, M.M. (2024). Application of geostatistical interpolation methods for filtration coefficients on the Nurkazgan East field using the Python programming language. Engineering Journal of Satbayev University, 146(1), 23-29. https://doi.org/10.51301/ejsu.2024.i1.04
- Mas’idah, E., & Marlyana, N. (2022). The study of the application of noise mapping using Golden Surfer Software to control noise. Journal of Applied Science and Technology, 2(02), 28-35. https://doi.org/10.30659/jast.2.02.28-35
