Study of rational solution parameters during in-situ uranium leaching
Shukhrat Alikulov1, Javokhir Toshov2, Ravil Mussin3, Mukhammedrakhym Rabatuly3, Bauyrzhan Tolovkhan3, Zhanbota Bogzhanova 3, Ayauzhan Gabitova3
1Navoi State University of Mining and Technologies, Navoi, Uzbekistan
2Tashkent State Technical University, Tashkent, Uzbekistan
3Abylkas Saginov Karaganda Technical University, Karaganda, Kazakhstan
Min. miner. depos. 2025, 19(1):37-46
https://doi.org/10.33271/mining19.01.037
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      ABSTRACT
      Purpose. The research aims to study and optimize the in-situ leaching (ISL) process for uranium mining using surface-active substances (surfactants) to improve the efficiency of uranium extraction from low-permeability ores.
      Methods. As part of the research, samples of low-permeability ores are taken and previously analyzed for porosity and filtration anisotropy coefficient, which is important for assessing their filtration properties. To study the effect of surfactants such as polyacrylamide, sulfanol and Mesh Drainage Liquid Filter (MDLF) compounds, solutions with different concentrations of these substances are prepared. Also, to determine the most effective surfactant concentrations, additional studies are conducted to optimize the leaching conditions, taking into account the effects of various factors such as temperature and pH of the solution. All the obtained results are mathematically analyzed to identify the optimal conditions, which helps to increase the efficiency of the uranium leaching process and improve the experimental results.
      Findings. In the course of the research conducted on the selection of surfactants for uranium leaching from low-permeability ores, the following results have been obtained. Sulfanol, as one of the surfactants used, shows the best results, significantly increasing the filtration coefficient from 0.5 to 2.0 m/day. This confirms its high efficiency in improving the ore horizon permeability and in accelerating the leaching process.
      Originality. The scientific novelty of the research is in the development of methods for optimal use of surface-active substances to improve the efficiency of the in-situ uranium leaching process from low-permeability ores. Studies have been conducted to determine the influence of various surfactants on the filtration properties of ores, as well as their in-fluence on accelerating the leaching process.
      Practical implications. The practical significance of the research is in the possibility of using the obtained data to optimize the in-situ uranium leaching process at real deposits with low-permeability of ore horizons. The developed recommendations on the selection of surfactants, such as sulfanol and polyacrylamide, as well as their optimal concentrations, can be directly applied to improve leaching efficiency, increase filtration coefficient, and reduce seam treatment time.
      Keywords: in-situ leaching, colmatation, sulfanol, polyacrylamide, porosity, anisotropy, filtration coefficient
      REFERENCES
- Demin, V., Kalinin, A., Baimuldin, M., Tomilov, A., Smagulova, A., Mutovina, N., Shokarev, D., Aliev, S., Akpanbayeva, A., & Demina, T. (2024). Developing a technology for driving mine workings with combined support and friction anchors in ore mines. Applied Sciences, 14(22), 10344. https://doi.org/10.3390/app142210344
- Kononenko, M., & Khomenko, O. (2010). Technology of support of workings near to extraction chambers. New Techniques and Technologies in Mining, 193-197. https://doi.org/10.1201/b11329-31
- Demin, V., Khalikova, E., Rabatuly, M., Amanzholov, Zh., & Zhumabekova, A. (2024). Research into mine working fastening technology in the zones of increased rock pressure behind the longwall face to ensure safe mining operations. Mining of Mineral Deposits, 18(1), 27-36. https://doi.org/10.33271/mining18.01.027
- Maussymbayeva, A.D., Yurov, V.M., Portnov, V.S., Rabatuly, M., & Rakhimova, G.M. (2024). Assessment of the influence of the surface layer of coals on gas-dynamic phenomena in the coal seam. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, 2, 5-11. https://doi.org/10.33271/nvngu/2024-2/005
- Bondarenko, V.I., Kharin, Ye.N., Antoshchenko, N.I., & Gasyuk, R.L. (2013). Basic scientific positions of forecast of the dynamics of methane release when mining the gas bearing coal seams. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, 5, 24-30.
- Maussymbayeva, A.D., Portnov, V.S., Imanbaeva, S.B., Rabatuly, M., & Rakhimova, G.M. (2024). Influence of rock shear processes on the methane content of longwall faces. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, 4, 11-17. https://doi.org/10.33271/nvngu/2024-4/011
- Wang, Z., Ren, T., & Cheng, Y. (2017). Numerical investigations of methane flow characteristics on a longwall face Part I: Methane emission and base model results. Journal of Natural Gas Science and Engineering, 43, 242-253. https://doi.org/10.1016/j.jngse.2017.03.029
- Bondarenko, V., Symanovych, G., & Koval, O. (2012). The mechanism of over-coal thin-layered massif deformation of weak rocks in a longwall. Geomechanical Processes During Underground Mining, 41-44. https://doi.org/10.1201/b13157-8
- Ostrogórski, P., Skotniczny, P., & Pucka, M. (2022). Measurements of the methane concentration along the longwall excavations and longwall. Archives of Mining Sciences, 67(1). https://doi.org/10.24425/ams.2022.140861
- Lian, G., An, Y., Sun, J., Yang, B., & Shen, Z. (2024). Effects and driving mechanisms of bioremediation on groundwater after the neutral in situ leaching of uranium. Science of the Total Environment, 946, 174406. https://doi.org/10.1016/j.scitotenv.2024.174406
- Wang, B., Luo, Y., Liu, J.H., Li, X., Zheng, Z.H., Chen, Q.Q., & Fan, Q.R. (2022). Ion migration in in-situ leaching (ISL) of uranium: Field trial and reactive transport modelling. Journal of Hydrology, 615, 128634. https://doi.org/10.1016/j.jhydrol.2022.128634
- Kitchen, H.J., Vallance, S.R., Kennedy, J.L., Tapia-Ruiz, N., Carassiti, L., Harrison, A., & Gregory, D.H. (2014). Modern microwave methods in solid-state inorganic materials chemistry: From fundamentals to manufacturing. Chemical Reviews, 114(2), 1170-1206. https://doi.org/10.1021/cr4002353
- Mukherjee, S., Goswami, S., & Zakaulla, S. (2023). Geological relationship between hydrocarbon and uranium: Review on two different sources of energy and the Indian scenario. Geoenergy Science and Engineering, 221, 111255. https://doi.org/10.1016/j.petrol.2022.111255
- Wang, Z., Song, H., Chen, Y., Song, J., Hou, M., Li, Q., & Yu, H. (2024). Uranium resource of Europe: Development status, metallogenic provinces and geodynamic setting. Energy Strategy Reviews, 54, 101467. https://doi.org/10.1016/j.esr.2024.101467
- Yang, H., Liu, Y., Chen, Z., Waterhouse, G. I., Ma, S., & Wang, X. (2022). Emerging technologies for uranium extraction from seawater. Science China. Chemistry, 65(12), 2335-2337. https://doi.org/10.1007/s11426-022-1358-1
- Tsoy, B.V., Myrzakhmetov, S.S., Bekbotaeva, A.A., & Yusupov, Kh.A. (2022). New geophysical logging techniques for practical problem solving at complex hydrogenetic uranium deposits. Gornyi Zhurnal, 7, 27-31. https://doi.org/10.17580/gzh.2022.07.04
- Stupnik, N.I., Fedko, M.B., Kolosov, V.A., & Pismennyy, S.V. (2014). Development of recommendations for choosing excavation support types and junctions for uranium mines of state-owned enterprise Skhidhzk. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, 5, 21-25.
- Yousufi, A., Ahmadi, H., Bekbotayeva, A., Arshamov, Y., Baisalova, A., Omarova, G., & Pekkan, E. (2023). Integration of remote sensing and field data in ophiolite investigations: A case study of Logar ophiolite complex, SE Afghanistan. Minerals, 13(2), 234. https://doi.org/10.3390/min13020234
- Mendygaliyev, A., Arshamov, Y., Selezneva, V., Yazikov, E., & Bekbotayeva, A. (2021). Prospects for application of multi-spectral earth sensing data in forecasting and searching for reservoir-infiltration uranium deposits. News of the National Academy of Sciences of the Republic of Kazakhstan, Series of Geology and Technical Sciences, 2(446), 90-97. https://doi.org/10.32014/2021.2518-170x.39
- Alikulov, S., Babayev, S., Alimov, M., Yuldoshev, A., & Sharopov, K. (2023). Research on the choice of the composition of the leaching solution during the extraction of gold by the method of underground leaching from used uranium wells. E3S Web of Conferences, 414, 01004. https://doi.org/10.1051/e3sconf/202341701004
- Lyashenko, V.I., Dudar, T.V., Stus, V.P., & Shapovalov, V.A. (2024). Justification of efficiency and subsoil protection during underground development of ore deposits using traditional technologies in combination with metals leaching. Mineral Resources of Ukraine, 2, 69-77. https://doi.org/10.31996/mru.2024.2.69-77
- Qiu, W., Yang, Y., Song, J., Que, W., Liu, Z., Weng, H., & Wu, J. (2025). A deep-learning-based multiobjective optimization for the design of in-situ uranium leaching system under multiple uncertainties. Journal of Hydrology, 651, 132576. https://doi.org/10.1016/j.jhydrol.2024.132576
- Liu, Y., He, Y., Chen, J., Cheng, N., & Wang, H. (2024). Progress on enhancing seepage-leaching mass-transfer research for in-situ leaching mining of low-permeability uranium-bearing sandstone: A review. Journal of Radioanalytical and Nuclear Chemistry, 333(9), 4485-4502. https://doi.org/10.1007/s10967-024-09585-5
- Abney, C.W., Mayes, R.T., Saito, T., & Dai, S. (2017). Materials for the recovery of uranium from seawater. Chemical Reviews, 117(23), 13935-14013. https://doi.org/10.1021/acs.chemrev.7b00355
- Yusupov, K.A., Rysbekov, K.B., Aben, K.K., & Bakhmagambetova, G.B. (2021). Increasing gold leaching efficiency with change of solution rheological properties. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, 3, 14-18. https://doi.org/10.33271/nvngu/2021-3/014
- Yussupov, K., Aben, E., Myrzakhmetov, S., Akhmetkanov, D., & Sarybayev, N. (2024). Increasing the efficiency of underground block leaching of metal. Civil Engineering Journal, 10(10), 3339-3349. https://doi.org/10.28991/CEJ-2024-010-10-014
- Zhang, L., Wen, B., Chen, L., Chen, H., & Wu, K. (2024). Variations in pore structures and permeabilities of ion adsorption rare earth ores during simulated in-situ leaching: Effect of newly formed clay particles and their swelling. Hydrometallurgy, 228, 106357. https://doi.org/10.1016/j.hydromet.2024.106357
- Khomenko, O., Rudakov, D., Lkhagva, T., Sala, D., Buketov, V., & Dychkovskyi, R. (2023). Managing the horizon-oriented in-situ leaching for the uranium deposits of Mongolia. Rudarsko Geolosko Naftni Zbornik, 38(5), 49-60. https://doi.org/10.17794/rgn.2023.5.5
- Vladyko, O., Maltsev, D., Sala, D., Cichoń, D., Buketov, V., & Dychkovskyi, R. (2022). Simulation of leaching processes of polymetallic ores using the similarity theorem. Rudarsko-Geolosko-Naftni Zbornik, 37(5), 169-180. https://doi.org/10.17794/rgn.2022.5.14
- Rysbekov, K.B., Kyrgizbayeva, D.M., Miletenko, N.A., & Kuandykov, T.A. (2024). Integrated monitoring of the area of Zhilandy deposits. Eurasian Mining, 41(1), 3-6. https://doi.org/10.17580/em.2024.01.01
- Rakishev, B.R., Bondarenko, V.I., Маtayev, M.M., & Kenzhetayev, Z.S. (2019). Influence of chemical reagent complex on intensification of uranium well extraction. Naukovyi Visnyk Natsionalnoho Hirnychoho Universytetu, 6, 25-30. https://doi.org/10.29202/nvngu/2019-6/4
- Yuan, Y., Yang, Y., Ma, X., Meng, Q., Wang, L., Zhao, S., & Zhu, G. (2018). Molecularly imprinted porous aromatic frameworks and their composite components for selective extraction of uranium ions. Advanced Materials, 30(12), 1706507. https://doi.org/10.1002/adma.201706507
- Bektay, E., Turysbekova, G., Shiderin, B., & Bektayev, M. (2024). Industrial application of bacterial iron oxidation in in-situ leaching technologies for uranium. Engineering Journal of Satbayev University, 146(5), 25-31. https://doi.org/10.51301/ejsu.2024.i5.04
- Chen, J., Zhao, Y., Song, Q., Zhou, Z., & Yang, S. (2018). Exploration and mining evaluation system and price prediction of uranium resources. Mining of Mineral Deposits, 12(1), 85-94. https://doi.org/10.15407/mining12.01.085
- Monnet, A., Gabriel, S., & Percebois, J. (2017). Long-term availability of global uranium resources. Resources Policy, 53, 394-407. https://doi.org/10.1016/j.resourpol.2017.07.008
- Jia, M., Luo, B., Lu, F., Yang, Y., Chen, M., Zhang, C., & Xu, Q. (2024). Improved FMM for well locations optimization in in-situ leaching areas of sandstone uranium mines. Nuclear Engineering and Technology, 56, 3750-3757. https://doi.org/10.1016/j.net.2024.04.023
- Nurpeisova, А., Shevko, V., Aitkulov, D., & Kushakova, L. (2023). Optimization of the electrothermal production of ferrosilicon from the leaching tailings of the oxidized copper ore of Almaly. Engineering Journal of Satbayev University, 145(1), 19-24. https://doi.org/10.51301/ejsu.2023.i1.03
- Li, G., & Yao, J. (2024). A review of in situ leaching (ISL) for uranium mining. Mining, 4(1), 120-148. https://doi.org/10.3390/mining4010009
- Sanakulov, K.S., Fuzaylov, O.U., & Kenbaeva, Zh.A. (2020). Microwave processing of sulphide gold concentrates. Gornyy Vestnik Uzbekistana, 1, 53-56.
- Chen, M., Yang, Y., Liu, W., Wang, C., & Johannessen, B. (2018). An in-situ synchrotron XAS study on the evolution of aqueous arsenic species in acid pressure leaching. Hydrometallurgy, 175, 11-19. https://doi.org/10.1016/j.hydromet.2017.10.016
- Khawassek, Y.M., Taha, M.H., & Eliwa, A.A. (2016). Kinetics of leaching process using sulfuric acid for Sella uranium ore material, South Eastern Desert, Egypt. International Journal of Nuclear Energy Science and Engineering, 6, 62-73. https://doi.org/10.14355/ijnese.2016.06.006
- Rakishev, B., Kenzhetaev, Z., Mataev, M., & Togizov, K. (2022). Improving the efficiency of downhole uranium production using oxygen as an oxidizer. Minerals, 12(8), 1005. https://doi.org/10.3390/min12081005
- Kuandykov, T.A., Karmanov, T.D., Kuldeyev, E.I., Yelemessov, K.K., & Kaliev, B.Z. (2022). New technology of uncover the ore horizon by the method of in-situ leaching for uranium mining. News of the National Academy of Sciences of the Republic of Kazakhstan, Series of Geology and Technical Science, 3, 142-154. https://doi.org/10.32014/2022.2518-170X.186
- Tsoy, B., Myrzakhmetov, S., Yazikov, E., Bekbotayeva, A., & Bashilova, Y. (2021). Application of radio-wave geointoscopy method to study the nature of spreading the solutions in the process of uranium underground leaching. Mining of Mineral Deposits, 15(4), 1-7. https://doi.org/10.33271/mining15.04.001
- Myrzakhmetov, B.А., Kuandykov, T.A., Mauletbekova, B.K., Balgayev, D.Y., & Nurkas, J.B. (2024). Multifunctional valve for the arrangement of submersible downhole pumps in downhole oil production. News of the National Academy of Sciences of the Republic of Kazakhstan, Series of Geology and Technical Sciences, 2(464), 156-168.https://doi.org/10.32014/2024.2518-170x.400
- Nazirova, A., Abdoldina, F., Aymahanov, M., Umirova, G., & Muhamedyev, R. (2016). An automated system for gravimetric monitoring of oil and gas deposits. Digital Transformation and Global Society, 585-595. https://doi.org/10.1007/978-3-319-49700-6_58
- Shakiyeva, T.V., Sassykova, L.R., Dzhatkambayeva, U.N., Khamlenko, A.A., Zhakirova, N.K., Batyrbayeva, A.A., Azhigulova, R.N., Kubekova, S.N., Zhaxibayeva, Z.M., Kozhaisakova, M.A., Sendilvelan, S., & Bhaskar, K. (2021). Optimization of the oxidative cracking of fuel oil on catalysts obtained from Kazakhstan raw materials. Rasayan Journal of Chemistry, 14(2), 1056-1071. https://doi.org/10.31788/RJC.2021.1426152
- Rabatuly, M., Myrzathan, S.A., Toshov, J.B., Nasimov, J., & Khamzaev, A. (2026). Views on drilling effectiveness and sampling estimation for solid ore minerals. Complex Use of Mineral Resources, 336(1), 5-14. https://doi.org/10.31643/2026/6445.01
- Sanakulov, K., Alikulov, S., Alimov, M., Yuldoshev, A., & Sharopov, K. (2024). Research of the movement of solutions in waterless dry horizons. E3S Web of Conferences, 525, 01001. https://doi.org/10.1051/e3sconf/202452501001
- Xie, Y., Wu, Y., Liu, X., Hao, M., Chen, Z., Waterhouse, G.I., & Ma, S. (2023). Rational design of cooperative chelating sites on covalent organic frameworks for highly selective uranium extraction from seawater. Cell Reports Physical Science, 4(1), 101220. https://doi.org/10.1016/j.xcrp.2022.101220