Mining of Mineral Deposits

ISSN 2415-3443 (Online)

ISSN 2415-3435 (Print)

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Impact of Artana mine on heavy metal pollution of the Marec river in Kosovo

Milaim Sadiku1, Sadija Kadriu1, Mensur Kelmendi1, Letafete Latifi2

1University of Mitrovica, Mitrovicë, 40000, Kosovo

2Hydrometeorological Institute of Kosovo, Prishtinë, 10000, Kosovo


Min. miner. depos. 2021, 15(2):18-24


https://doi.org/10.33271/mining15.02.018

Full text (PDF)


      ABSTRACT

      Purpose. This paper aims to reflect the extent of the impact of the Artana mine on heavy metal pollution of the waters of the Marec river. Mineralogical pollution of this river resulted in almost total degradation of biota.

      Methods. To be as realistic as possible in assessing the water quality of the Marec river and of a single spring located in the research area and used for drinking, we have applied the standard methods ISO 5667-6 for surface water and ISO 5667-11 for groundwater. The sampling and the quantity of the samples, as well as their transportation, was done in full compliance with the ISO 5667-1.3 method. Whereas, the conservation of samples taken for the determination of heavy metals is done according to the APHA conservation procedure. For the extraction (mineralization) of heavy metals in the samples taken, the EPA-3015A method was applied, while for the determination of the concentration of heavy metals the SAA (Atomic Absorption Spectrophotometry) measurement technique was applied.

      Findings. As a result of the industrial activity of the Artana mine, it has been ascertained that the main causes of the pollution of the Marec river waters and the habitat around it is the mineral exploitation activity in this industrial complex. Analysis of water samples discharged from the mine, flotation and drainage of landfills reflect the real state of heavy metals concentration in the Marec river.

      Originality. In order for the results to realistically reflect the degree of heavy metals concentration in the waters of this river, we have implemented existing and advanced analytical techniques.

      Practical implications. The water samples from the Marec river were taken and analyzed in January and July 2020. The analysis performed showed significant exceedance of heavy metals concentration in all sampling sites located in the studied industrial area.

      Keywords: mine of Artana, Marec river, landfill, streams, heavy metals, pollution


      REFERENCES

  1. Kadriu, S., Sadiku, M., Kelmendi, M., Mulliqi, M., Aliu, M., & Hyseni, A. (2019). Scale of pollutions with heavy metals in water and sediment of River Ibër from landfill in Kelmend, Kosovo. Mining Science, (26), 147-155. https://doi.org/10.37190/msc192610
  2. Kadriu, S., Sadiku, M., Kelmendi, M., & Sadriu, E. (2020). Studying the heavy metals concentration in discharged water from the Trepça Mine and flotation, Kosovo. Mining of Mineral Deposits, 14(4), 47-52. https://doi.org/10.33271/mining14.04.047
  3. Raport Hotspotet Mjedisore në Kosovë. (2011). Agjencia për Mbrojtjen e Mjedisit të Kosovës. Prishtinë, Kosovës: Agjencia për Mbrojtjen e Mjedisit të Kosovës. Available at:https://www.ammk-rks.net/repository/docs/raporti_i_hotospoteve_shqip_18122012.pdf
  4. Schmitt, O.J. (2009). Skënderbeu. Përkthimi në shqip me ndihmën Swiss Agency for Development and Cooperation SDC. Retrieved from https://peshkupauje.com/t/i-pafani-skenderbej-i/3883
  5. Kadriu, S., Sadiku, M., Kelmendi, M., & Shala, A. (2021). The impact of polluting sources on the physical-chemical properties of water in the curved river in Kosovo. Journal of Environmental Treatment Techniques, 9(2), 368-374. https://doi.org/10.47277/JETT/9(2)374
  6. Bogdanović, G., Antonijević, M., Milanović, Z., Šerbula, S., & Milić, S. (2007). Analiza stanja rudničkih voda Rudnika bakra Bor. In II Simpozijum “Reciklažne tehnologije i održivi razvoj” (pp. 269-275). Soko Banja, Srbija.
  7. Sadiku, M., Kadriu, S., Kelmendi, M., & Aliu, M. (2020). Ndikimi i ujërave të minierës dhe deponive industriale të Artanës në ndotjen mjedisore. In 2nd iInternational Multidisciplinary Geosciences Conference. Geosciences and Sustainable Development (pp. 142-147). Mitrovicë, Kosovo.
  8. Kadriu, S., Malollari, I., Beqiri, L., Aliu, M., Sadiku, M., Baruti, B., & Kelmendi, M. (2017). Presence of heavy metals in water and sediment of rivers Trepca and Sitnica. Journal of Environmental Protection and Ecology, 18(1), 10-21.
  9. Hilson, G. (2000). Pollution prevention and cleaner production in the mining industry: an analysis of current issues. Journal of Cleaner Production, 8(2), 119-126. https://doi.org/10.1016/S0959-6526(99)00320-0
  10. Wei, W., Ma, R., Sun, Z., Zhou, A., Bu, J., Long, X., & Liu, Y. (2018). Effects of mining activities on the release of heavy metals (HMs) in a typical mountain headwater region, the Qinghai-Tibet Plateau in China. International journal of Environmental Research and Public Health, 15(9), 1987. https://doi.org/10.3390/ijerph15091987
  11. Malik, N., Biswas, A.K., Qureshi, T.A., Borana, K., & Virha, R.(2009). Bioaccumulation of heavy metals in fish tissues of a freshwater lake of Bhopal. Environmental Monitoring and Assessment, 160(1-4), 267-276. https://doi.org/10.1007/s10661-008-0693-8
  12. Çullaj, A. (2010). Kimia e mjedisit. Tirana, Albania.
  13. Sadiku, M., Shala, F., Hoda, S., Sadiku, A., Lajçi, N., & Kadriu, S. (2016). Impact of zinc’s cake in groundwater pollution. Journal of International Environmental Application & Science, 11(1), 72-76.
  14. Kadriu, S., Sadiku, M., Kelmendi, M., Tahiraj, B., Aliu, M., Hyseni, A., & Shala, A. (2020). Research of the drinking water quality in wells and fountains of villages in gjakova municipality in Kosovo. Journal of Environmental Treatment Techniques, 8(3), 1151-1156.
  15. ISO 5667-6. (2014). Water quality – Sampling – Part 6: Guidance on sampling of rivers and streams.
  16. ISO 5667-11. (2009). Water quality – Sampling – Part 11: Guidance on sampling of groundwaters.
  17. ISO 5667-1. (2006). Water quality – Sampling – Part 1: Guidance on the design of sampling programmes and sampling techniques.
  18. ISO 5667-3. (2012). Water quality – Sampling – Part 3: Preservation and handling of water samples.
  19. APHA, AWWA, WEF. (2005). Standard methods for the examination of water and wastewater. New York, United States: American Public Health Association.
  20. EPA Method 3015. (1994). Microwave assisted acid digestion of aqueous samples and extracts. Pittsburgh, United States: Duquesne University.
  21. Udhëzimi Administrativë e MMPH-Nr. 30/2014 të Kosovës, për kushtet, mënyrat, parametrat dhe vlerat kufizuese të shkarkimit të ujërave të ndotura në rrjetin e kanalizimit publik dhe në trupin ujor. (2014). Available at: https://mmph.rks-gov.net/assets/cms/uploads/files/Publikimet/Kalendari/ministri-ua-30-2014_785221.pdf
  22. Vlerat maksimale të lejuara për disa metale të rënda në ujërat sipërfaqësor sipas Dekretit Legjislativ 11 Maj 1999 Nr. 15232. (2015). Raport për gjendjen e ujërave në Republikën e Kosovës, Ministria e Mjedisit dhe Planifikimit Hapsinor. Prishtinë. Available at: https://www.ammk-rks.net/repository/docs/Raporti_i_ujrave_i_2015_shqip_(2).pdf
  23. Udhëzimi Administrativ Nr. 16/2012. (2012). Për cilësinë e ujit për konsum nga njeriu, të Kosovës. Retrieved from https://gzk.rks-gov.net/ActDetail.aspx?ActID=10134
  24. Halysh, V., Trus, I., Gomelya, M., Trembus, I., Pasalskiy, B., Chykun, N., Trokhymenko, G., & Remeshevska, I. (2020). Utilization of modified biosorbents based on walnut shells in the processes of wastewater treatment from heavy metal ions. Journal of Ecological Engineering, 21(4), 128-133. https://doi.org/10.12911/22998993/119809
  25. Terrence, T., John, F., Shoichi, K., Darryl, J., Stephen, A., & Philip, C. (2007). Chemical safety of drinking water: assessing priorities for risk management. Geneva, Switzerland: World Health Organization. Available at:https://apps.who.int/iris/bitstream/handle/10665/43285/9789241546768_eng.pdf
  26. Robards, K., & Worsfold, P. (1991). Cadmium toxicology and analysis – A review. Analyst, 116(6), 549-568.https://doi.org/10.1039/an9911600549
  27. Лицензия Creative Commons